Chris Evans

Steve Rogers / Captain America

Samuel L. Jackson

Nick Fury

Scarlett Johansson

Natasha Romanoff / Black Widow

Robert Redford

Alexander Pierce

Sebastian Stan

Bucky Barnes / Winter Soldier

Anthony Mackie

Sam Wilson / Falcon

Cobie Smulders

Maria Hill

Frank Grillo

Brock Rumlow

Maximiliano Hernández

Jasper Sitwell

Emily VanCamp

Kate / Agent 13

Hayley Atwell

Peggy Carter

Toby Jones

Dr. Arnim Zola

Stan Lee

Smithsonian Guard

Callan Mulvey

Jack Rollins

Jenny Agutter

Councilwoman Hawley

Bernard White

Councilman Singh

Alan Dale

Councilman Rockwell

Chin Han

Councilman Yen

Garry Shandling

Senator Stern

Georges St-Pierre

Georges Batroc

Salvator Xuereb

French Pirate #1

Brian Duffy

French Pirate #2

Zack Duhame

Engine Pirate

Adetokumboh M'Cormack

French Radio Pirate

Christopher George Sarris

Skinny Steve

Aaron Himelstein

Launch Tech #1

Allan Chanes

Launch Tech #2

Joe Russo

Dr. Fine

Christopher Markus

SHIELD Interrogator #1

Stephen McFeely

SHIELD Interrogator #2

Pat Healy

Scientist #1

Ed Brubaker

Scientist #2

D.C. Pierson

Apple Employee

Danny Pudi

Com Tech #1

Bernie Zilinskas

Com Tech #2

Branka Katić

Renata

Angela Russo-Otstot

Garcia

Jon Sklaroff

Charlie XO

Chad Todhunter

Charlie Weapons Tech

Abigail Marlowe

SHIELD Tech

Jeremy Maxwell

Lead SHIELD Pilot

Emerson Brooks

Senior SHIELD Agent

Evan Parke

SHIELD Agent

Ricardo Chacon

Strike SGT. #1

Griffin M. Allen

Strike SGT. #2

Ann Russo

Strike Agent

Joe Rosalina

Strike Agent

Michael Debeljak

Strike Agent

Eddie J. Fernandez

Strike Agent

Jody Hart

25ᵗʰ Floor Strike Agent

Steven Culp

Scudder

Derek Hughes

Human Resources Executive

Wendy Hoopes

Doctor

Ethan Rains

Lead EMT

Dominic Rains

CIA Instructor

Charles Wittman

Capitol Hill Police

Andy Martinez, Jr.

Capitol Hill Police

Michael De Geus

FBI Agent

Terence O'Rourke

FBI Agent

Anne Grimenstein

Committee Member

Dante Rosalina

Little Boy in the Smithsonian

Robert Clotworthy

Fury Car Voice (voice)

June Christopher

SHIELD Computer (voice)

Gary Sinise

The Smithsonian Narrator (voice)

Henry Goodman

Dr. List (uncredited)

Dean Barlage

SHIELD Agent (uncredited)

Joel Thingvall

Museum Visitor (uncredited)

Thomas Kretschmann

Baron Wolfgang von Strucker (uncredited)

Elizabeth Olsen

Wanda Maximoff / Scarlet Witch (uncredited)

Nestor Serrano

Committee General (uncredited)

Aaron Taylor-Johnson

Pietro Maximoff / Quicksilver (uncredited)

Joss Whedon

Man on Escalator in Museum (uncredited)

James Lewis

Smithsonian Museum Visitor

Josh Heileman

S.H.I.E.L.D. Strike Agent (uncredited)

Dominique Henderson

Pedestrian (uncredited)